DXF files import exactly as created, you cannot re-scale as you would lose quality.
If you set the size correctly in Inkscape and export in mm the size is very close, it isn't perfect as I've documented but that's a bug within Inkscape and the way it stores information internally.
If you use TurboCAD, it is exactly the dimensions you save.
I still have a note to make a tutorial on exporting DXF's correctly but haven't had time.
- Zax